Zhejiang Xinhua Chemical Co., Ltd.
Zhejiang Xinhua Chemical Co., Ltd.

ETHYLAMINE
ICSC: 0153
October 2002
Ethanamine
Aminoethane
PDF file for printing Explanation of fields
CAS # 75-04-7 ( Cylinder ) C2H5NH2 / C2H7N
RTECS # KH2100000 Molecular mass : 45.1
UN # 1036
EC # 612-002-00-4
Types of hazard / Exposure Acute hazards / Symptoms Prevention First aid / Fire fighting
Fire Extremely flammable. Gives off irritating or toxic fumes (or gases) in a Fire. NO open flames, NO sparks, and NO smoking. Shut off supply; if not possible and no risk to surroundings, let the Fire burn itself out; in other cases extinguish with dry powder, carbon dioxide.
Explosion Gas/air mixtures are explosive. Closed system, ventilation, Explosion-proof electrical equipment and lighting. In case of Fire: keep cylinder cool by spraying with water. Combat Fire from a sheltered position.
Exposure   Strict hygiene!  
Inhalation Cough. Laboured breathing. Sore throat. Ventilation, local exhaust, or breathing protection. Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention.
Skin ON CONTACT WITH LIQUID: FROSTBITE. Cold-insulating gloves. Protective clothing. ON FROSTBITE: rinse with plenty of water, do NOT remove clothes. Refer for medical attention.
Eyes Redness. Pain. Blurred vision. Safety goggles, or eye protection in combination with breathing protection. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
Ingestion   Do not eat, drink, or smoke during work.  
Spillage disposal Packaging & Labelling
Evacuate danger area! Consult an expert! Ventilation. Remove all ignition sources. NEVER direct water jet on liquid. (Extra personal protection: complete protective clothing including self-contained breathing apparatus.) F+ Symbol
Xi Symbol
R: 12-36/37
S: (2-)16-26-29
UN Hazard Class: 2.1
Emergency response Storage
Transport Emergency Card: TEC (R)-20G2F
NFPA Code: H 3; F 4; R 0
Fireproof. Cool.
Important data
Physical State; Appearance
Colourless compressed liquefied gas, With pungent odour.
Physical dangers
The gas is heavier than air and may travel along the ground; distant ignition possible.
Chemical dangers
The substance decomposes on burning producing toxic gases including nitrogen oxides. The solution in water is a strong base, it reacts violently with acid and is corrosive. Reacts violently with strong oxidants and organic compounds causing Fire and Explosion hazard. Attacks many non-ferrous metals and plastic.
Occupational Exposure limits
TLV: 5 ppm as TWA; 15 ppm as STEL; (skin); (ACGIH 2002).MAK: 5 ppm; 9.4 mg/m3; Peak limitation category: I(2);MAK: class Pregnancy risk group: IIc (2002).EU OEL: 5 ppm; 9.4 mg/m3; (EU 2002).
Routes of Exposure
The substance can be absorbed into the body by inhalation.
Inhalation risk
On loss of containment, a harmful concentration of this gas in the air will be reached very quickly.
Effects of short-term Exposure
The substance is severely irritating to the eyes and the respiratory tract. Rapid evaporation of the liquid may cause frostbite.
Physical properties
Boiling point: 16.6oC
Melting point: -81oC
Relative density (water = 1): 0.7 (liquid)
Solubility in water: miscible
Vapour pressure, kPa at 20oC: 121
Relative vapour density (air = 1): 1.55
Relative density of the vapour/air-mixture at 20oC (air = 1): 1.66
Flash point: -17oC c.c.
Auto-ignition temperature: 385oC
Explosive limits, vol% in air: 3.5-14
Octanol/water partition coefficient as log Pow: -0.27/-0.08 (calculated)
Environmental data
The substance is harmful to aquatic organisms.
Notes
Ethylamine is available commercially also in the form of 50-70% aqueous solution (UN number: 2270).
Turn leaking cylinder with the leak up to prevent escape of gas in liquid state.
IPCS
International
Programme on
Chemical Safety
Prepared in the context of cooperation between the International Programme on Chemical Safety and the European Commission
© IPCS 2002
Legal notice Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information.